高翔(Xiang Gao)

Ph.D. (2013-2017) 

Dalian Institute of Chemical Physics, 
Chinese Academy of Sciences, 
457 Zhongshan Road, Dalian 116023, P. R. China

Tel: 86-411-84379325 (office)
E-mail: gxwr9007@126.com

 

Educational and Professional Background:

2013.9-2017.5, Ph. D. in Organic Chemistry, Advisor Prof. Yong-Gui Zhou, Dalian Institute of Chemical Physics, CAS.

2012.9-2013.7, Graduate Course, University of Science and Technology of China.

2008.9-2012.7, B.S. in Chemical Engineering and Technology, Hunan University.

 

Awards:

 
 
Representative Publications:
14. Zhong Yan, Xiang Gao and Yong-Gui Zhou.* Enantioselective Synthesis of Quaternary α-amino- phosphonates by Organocatalytic Friedel–Crafts Reactions of Indoles with Cyclic α-ketiminophosphonates. Chin. J. Catal. 2017, 38, 784-792.


                         
                                               


                     

13. Bo Wu, Zhaoyuan Yu, Xiang Gao,  Yu Lan* and Yong-Gui Zhou.* Regioselective α-Addition of Deconjugated Butenolides: Enantioselective Synthesis of Dihydrocoumarins. Angew. Chem. Int. Ed. 2017, 56, 4006-4010.



                         
                                               



12. Ji Zhou, Mao-Lin Wang, Xiang Gao, Guo-Fang Jiang* and Yong-Gui Zhou.* Bifunctional Squaramide-catalyzed Synthesis of Chiral Dihydrocoumarins via ortho-Quinone Methides Generated from 2-(1-tosylalkyl)phenols. Chem. Commun. 2017, 53, 3531-3534.



                         
                                               



11. Hong-Qiang Shen, Xiang Gao,  Cong Liu, Shu-Bo Hu and Yong-Gui Zhou.* A Hydrogenation/Oxidative Fragmentation Cascade for Synthesis of Chiral 4,5-Dihydro-1H-benzo[d]azepin-1-ones. Org. Lett. 2016, 18,  5920-5923.



                                               



10. Xiang Gao, Bo Wu,  Zhong Yan and Yong-Gui Zhou.* Copper-catalyzed Enantioselective C–H Functionalization of Indoles with an Axially Chiral Bipyridine Ligand. Org. Biomol. Chem. 2016, 14, 8237-8240.




                                             



9. Zhong Yan, Bo Wu, Xiang Gao and Yong-Gui Zhou.* Enantioselective Synthesis of Quaternary α-aminophosphonates by Pd-catalyzed Arylation of Cyclic α-ketiminophosphonates with Arylboronic Acids. Chem. Commun. 2016, 52, 10882-10885.




                                               



8. Zhong Yan, Bo Wu, Xiang Gao, Mu-Wang Chen  and Yong-Gui Zhou.* Enantioselective Synthesis of α-Amino Phosphonates via Pd-Catalyzed Asymmetric Hydrogenation. Org. Lett. 2016, 18, 692–695.



                     



7. Bo Wu, Xiang Gao, Zhong Yan, Mu-Wang Chen, and Yong-Gui Zhou.* C-H Oxidation/Michael Addition/Cyclization Cascade for Enantioselective  Synthesis of Functionalized 2-Amino-4 H-chromenes. Org. Lett. 2015, 17, 6134-6137.                                  



                     



6. Xiang Gao, Bo Wu, Zhong Yan, and Yong-Gui Zhou.* Enantioselective Palladium-catalyzed Arylation of N-tosylarylimines with Arylboronic Acids Using a Chiral 2,2’-bipyridine Ligand. Org. Biomol. Chem. 2016, 14, 55-58.



                     



5. Xiang Gao, Bo Wu, Wen-Xue Huang, Mu-Wang Chen, and Yong-Gui Zhou.* Enantioselective Palladium-Catalyzed C-H Functionalization of Indoles Using an Axially Chiral 2,2’-Bipyridine Ligand. Angew. Chem. Int. Ed. 2015, 54, 11956-11960.


                     


4.  Bo Wu, Xiang Gao, Zhong Yan, Wen-Xue Huang, and Yong-Gui Zhou.* Enantioselective Synthesis of Functionalized 2-Amino-4H-chromenes via the o-Quinone Methides Generated from 2-(1-Tosylalkyl) phenols. Tetrahedron Lett. 2015, 56, 4334-4338.



                     


3.  Wen-Xue Huang, Bo Wu, Xiang Gao, Mu-Wang Chen, Baomin Wang,*                          and Yong-Gui Zhou.* Iridium-Catalyzed Selective Hydrogenation of 3-Hydroxypyridinium                          Salts: A Facile Synthesis of Piperidin-3-ones. Org. Lett. 2015, 17, 1640-1643.



                     


2.  Bo Wu, Xiang Gao, Mu-Wang Chen and Yong-Gui Zhou.* Direct Amination of 2-(1-tosylalkyl) phenols with Aqueous Ammonia:                            a Metal-free Synthesis of Primary Amines. Tetrahedron Lett. 2015, 56,  1135–1137.



                     


1. Bo Wu, Xiang Gao, Mu-Wang Chen, and Yong-Gui Zhou.* A Concise Synthesis of 2-(2-Hydroxy-phenyl) acetonitriles via the o-Quinone Methides Generated from 2-(1-Tosylalkyl)phenols. Chin. J. Chem. 2014, 32, 981-984.

< Cover Article 2014, 32, 10 >



 


 
 

中国科学院大连化学物理研究所 手性合成研究组 版权所有
 Copyright  Chiral Synthesis, Laboratory of Fine Chemicals. Dalian Institute of Chemical Physics (DICP) , CAS. All Rights Reserved.